In real life to create gunpower you need mix sulfur with charcoal and potassium nitrate. The natural source of potassium nitrate is guano, the poops of bats. Minecraft already has bats but making them spawn guano like a chicken its eggs would worse performance, killing bats for their guano I guess won't be done by Mojang, so I suggest feeding bats with spider eyes which will make them produce guano as they eat insects. Casual and especially Peaceful Mode players have the hardest time getting gunpower in big amounts.
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