First, you need to earn the witch's trust. Under no circumstances should you hit her, otherwise, it will be destroyed forever. You need to give her >20 nether wart/blaze powder/blaze rods (that is, the stuff used for potion brewing, not flasks or gunpowder).
She will stop attacking the player but remain a neutral mob. If you throw her an emerald, she will exchange potion ingredients with the player (~5 pufferfish/gunpowder/sugar/spider eye, etc.).
After such contact, you can throw her a potion as an item (required to have an effect). The icon on the witch's hat will change color, and she will be able to sell random items in larger quantities (~10). Afterwards, you can throw her an explosive potion as an item; ender pearls, so she can sell more valuable items later.
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