Tin ore, and bronze!
Tin ore can be found underground similar to copper, it spawns in veins like coppers and generates on the same layers as copper. It drops 1 tin ore and can be smelted into tin ingots. It can be combined with copper at a smithing table to create bronze ingots. Bronze ingots can make armor and tools using the same reicipe as every other armor adn tool, and can even make a sheild that is circular instead of square but functions the same as a regular shield. The armor and tools will be slightly better than iron, but worse than diamond, and can't mine obsidian.
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